Polymer Supported Zinc Borohydride: A Stable, Efficient, Selective, and Regenerable Reducing Agent for Variety of Organic Compounds

نویسندگان

  • Bahman Tamami Department of Chemistry, Faculty of Science, Shiraz University, Postcode 71454, Shiraz, I.R. IRAN
  • Moredin Goudarzian Department of Chemistry, Faculty of Science, Shiraz University, Postcode 71454, Shiraz, I.R. IRAN
چکیده مقاله:

The difficult to handle and store zinc borohydride, Zn(BH4)2, is stabilized by supporting it on polyvinylpyridine. This new mild, efficient, selective, and regenerable polymer supported borohydride reducing agent reduces a variety organic compounds such as, aldehydes, a-b-unsaturated carbonyl compounds, acid chlorides, epoxides, disulfides, as well as reductive acetylation of carbonyl compounds. It absolutely discriminates aldehydes from ketones.  

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عنوان ژورنال

دوره 15  شماره 2

صفحات  63- 71

تاریخ انتشار 1996-12-01

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